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West Virginia State Police ( So.Charleston Trp.4 ) - Talk Group 9011 - On WV SIRN P25
Kanawha County Sheriff - 155.625 Ctcss 179.9 - Conventional
Kanawha County Sheriff - Talk Group 6120 - On WV SIRN P25
Eastern Kanawha County Municipal Cities Police, Park Police and WV State University Police - TG 6121 - On WV SIRN P25
Kanawha County Fire 1 - 155.145 Dcs 343 - Conventional
Kanawha County Fire 2 - 155.745 Ctcss 103.5 - Conventional
Kanawha County Fire 3 - 145.280 Ctcss 103.5 - Conventional
Kanawha County Fire 4 - 153.830 Ctcss 103.5 - Conventional
Kanawha County Fire Repeater - 453.100 Dcs 723 - Conventional
Kanawha County Fire Repeater - 453.9875 Dcs 346 - Conventional
Kanawha County Fire 1 - Talk Group 6140 - On WV SIRN P25
Kanawha County Fire 2 - Talk Group 6141 - On WV SIRN P25
Kanawha County Fire 3 - Talk Group 6142 - On WV SIRN P25
Kanawha County Fire 4 - Talk Group 6143 - On WV SIRN P25
Kanawha County Ems East - 151.100 Ctcss 156.7 - Conventional
Kanawha County Ems West - 151.100 Ctcss 162.2 - Conventional
Kanawha County Ems 1 (ALS) - Talk Group 6150 - On WV SIRN P25
Charleston PD 1 - 159.150 Ctcss 151.4 - Conventional
Charleston PD 1 - Talk Group 6220 - On WV SIRN P25
Charleston Fire/Ems 1 - Talk Group 6210 - On WV SIRN P25
Charleston Fire 2 - Talk Group 6211 - On WV SIRN P25
Charleston Ems - Talk Group 6214 - On WV SIRN P25
Dunbar Police 1 - 154.055 Ctcss 151.4 - Conventional
Dunbar Police 1 - Talk Group 6117 - On WV SIRN P25
Dunbar Fire - 154.965 Dcs 025 - Conventional
So. Charleston Police 1 - 158.790 Ctcss 131.8 - Conventional
So. Charleston Police 1 - Talk Group 6118 - On WV SIRN P25
So. Charleston Fire - Talk Group 6136 - On WV SIRN P25
St. Albans / Nitro Police - Talk Group 6122 - On WV SIRN P25
St. Albans / Nitro Fire - Talk Group 6130 - On WV SIRN P25
St. Albans / Nitro Fire - 151.025 Ctcss 173.8 - Conventional

Here is a link to Scanner Frequencies that are active in Kanawha County.Radio Reference.com